The user manual states that the output voltage of this unit is 120V - it makes no mention of being able to stack these to produce 220V power. There are inverters that are capable of being stacked but this doesn't appear to be one. You may be able to get a step-up transformer to turn 120 to 240V and use that, but it would likely be easier and safer to get an inverter set that does it out of the box for ease of installation etc.
Nature Power Pure Sine Wave Power Inverter and Charger, 6,000 Surge Watts, 3,000 Rated Watts

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- High 6,000 Watt surge power rating to start demanding AC loads
- Includes a built-in 150 Amp charger to help you charge your battery bank in the fastest way possible
- Automatic transfer switch allows seamless transfer from shore or RV campground AC power to inverter/battery power
- Remote control panel with 30ft. network cable provides system information and allows for unit setup wherever you install it
- Automatic AC load sensing, overload protection, high temperature shutdown, over-voltage protection, low voltage alarm and low voltage shutdown for safety
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